@Article{MirandaBaldBeloFerr:2011:NaInPo,
author = "Miranda, Claudia Renata Borges and Baldan, M. R. and Beloto,
Antonio Fernando and Ferreira, Neiden{\^e}i Gomes",
affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Instituto Nacional de
Pesquisas Espaciais (INPE)} and {Instituto Nacional de Pesquisas
Espaciais (INPE)}",
title = "Nanodiamond infiltration into porous silicon through etching of
solid carbon produced at different graphitization temperatures",
journal = "Journal of Nanoparticle Research",
year = "2011",
volume = "13",
number = "9",
pages = "4219--4228",
month = "Sept.",
note = "{Setores de Atividade: Pesquisa e desenvolvimento
cient{\'{\i}}fico.}",
keywords = "Nanodiamond, Porous silicon, Chemical vapor infiltration,
Reticulated vitreous carbon, Synthesis, NANOCRYSTALLINE DIAMOND
FILMS, RETICULATED VITREOUS CARBON, CHEMICAL-VAPOR-DEPOSITION,
HF-ACETONITRILE, GROWTH, NUCLEATION, FABRICATION, ETHANOL,
SURFACE, CVI.",
abstract = "Nanocrystalline diamond (NCD) was grown on the porous silicon (PS)
substrate using Reticulated Vitreous Carbon (RVC) as an additional
solid carbon source. RVC was produced at different heat treatment
temperatures of 1300, 1500, and 2000 °C, resulting in samples with
different turbostratic carbon organizations. The PS substrate was
produced by an electrochemical method. NCD film was obtained by
the chemical vapor infiltration/deposition process where a RVC
piece was positioned just below the PS substrate. The PS and NCD
samples were characterized by Field Emission Gun-Scanning Electron
Microscopy (FEG-SEM). NCD films presented faceted nanograins with
uniform surface texture covering all the pores resulting in an
apparent micro honeycomb structure. Raman's spectra showed the D
and G bands, as well as, the typical two shoulders at 1,150 and
1,490 cm\−1 attributed to NCD. X-ray diffraction analyses
showed the predominant (111) diamond orientation as well as the
(220) and (311) peaks. The structural organization and the
heteroatom presence on the RVC surface, analyzed from X-ray
photoelectron spectroscopy, showed their significant influence on
the NCD growth process. The hydrogen etching released, from RVC
surface, associated to carbon and/or oxygen/nitrogen amounts led
to different contributions for NCD growth.",
doi = "10.1007/s11051-011-0366-3",
url = "http://dx.doi.org/10.1007/s11051-011-0366-3",
issn = "1388-0764",
label = "lattes: 3894119234731870 3 MirandaBaldBeloFerr:2011:NaInIn",
language = "en",
targetfile = "miranda.pdf",
urlaccessdate = "13 maio 2024"
}